TY - BOOK AU - Verkade, John G AU - Verkade, John G. TI - A Pictorial approach to molecular bonding and vibrations SN - 9781461384977 U1 - 541.224 VER 2nd ed. PY - 1997/// CY - New York PB - : Springer, KW - Chemistry KW - Physical chemistry KW - Chemical bonds KW - Molekülorbital KW - Chemische Bindung KW - Spectres de vibration KW - Atomic N1 - Ch. 1. Orbital Picture for Bound Electrons -- Ch. 2. Atomic Orbitals -- Ch. 3. Diatomic Molecules -- Ch. 4. Linear Triatomic Molecules -- Ch. 5. Triangular and Related Molecules -- Ch. 6. Bent Triatomic Molecules -- Ch. 7. Polygonal Molecules -- Ch. 8. Octahedral and Related Molecules -- Ch. 9. Tetrahedral and Related Molecules -- Ch. 10. Bipyramidal and Related Molecules -- Ch. 11. Prismatic Molecules -- Ch. 12. Polymers -- Ch. 13. Cages -- Ch. 14. Solid State Materials -- App. I.A. Wave Amplitude -- App. I.B. Normalization and Orthogonality -- App. I.C. Using an Orbital Matrix -- App. II. A. Integrating an Orbital Wave Function -- App. II. B. Calculating the Angles for Conal Nodes -- App. II. C. Mathematical Meaning of R -- App. II. D. Mathematical Meaning of R* -- App. II. E. Mathematical Meaning of v(nlm) -- App. II. F. Kinetic and Total Electronic Energy -- App. II. G. Reorienting a Set of (p) Orbitals -- App. II. H. Linearly Combining (2s), (2px), (2py), and (2pz) -- App. II. I. Angle between Orthogonal Digonal sp Hybrids -- App. II. J. Transformation Matrix for sp Digonal Hybrids -- App. II. K. Reorienting sp Digonal Hybrids -- App. II. L. Transformation Matrix for sp[superscript 2] Trigonal Hybrids -- App. II. M. Transformation Matrix for sp[superscript 3] Tetrahedral Hybrids -- App. II. N. Gradual Changes in Character between Two Orbitals -- App. II. O. Relationship between Trigonal and Tetrahedral Hybrids -- App. III. A. Symmetry, Molecular Orbitals, and Generator Orbitals -- App. III. B. Overlap Integral -- App. III. C. Kit for Visualizing MOs in Three Dimensions -- App. IV. Hybrid GOs and Noncooperating Central Atoms -- App. V. Circular Nodes in Rectangularly Shaped Molecules -- App. VI. Euler's Theorem and Cages -- App. VII. Huckel Calculations N2 - Understanding molecular orbitals (MOs) is a prerequisite to appreciating many physical and chemical properties of matter. This extensively revised second edition of A Pictorial Approach to Molecular Bonding presents the author's innovative approach to MOs, generating them pictorially for a wide variety of molecular geometries ER -